EVALUASI KINERJA DAN MEKANISME ADSORPSI EKSTRAK KULIT BATANG POHON KAPUK SEBAGAI INHIBITOR KOROSI PADA STAINLESS STEEL 304
Keywords:
Stainless steel, Inhibitor alam, Korosi logam, Adsorpsi isotermalAbstract
Penelitian ini berupaya meningkatkan kemampuan ekstrak kulit batang pohon kapuk sebagai inhibitor korosi ramah lingkungan untuk stainless steel 304 (SS) dalam media 1 M HCl. Untuk menilai efektivitas dan mekanisme ekstrak tersebut dalam menghambat korosi, digunakan metode investigasi seperti pengujian eksperimen Polarisasi Potensiodinamik (PDP) dan analisa adsorpsi Isotermal. Temuan eksperimen PDP menunjukkan bahwa kemampuan penghambatan ekstrak sangat dipengaruhi oleh konsentrasinya, dengan efisiensi mencapai 74.72% pada konsentrasi 3000 mg/L. Data PDP mengonfirmasi bahwa inhibitor ini bertindak sebagai inhibitor campuran yang efektif dalam memperlambat proses korosi pada stainless steel. Selain itu, perilaku adsorpsi ekstrak mengikuti model isoterm Langmuir dan bersifat kemisorpsi dan fisisorpsi seperti terjadinya interaksi elektrostatik antara inhibitor yang terionisasi dengan permukaan logam dan melibatkan pembentukan ikatan kovalen. Secara keseluruhan, mekanisme terjadi melalui proses adsorpsi heteroatom seperti oksigen (O), nitrogen (N), sulfur (S), fosfor (P), dan struktur molekul cincin aromatik dari ekstark kulit batang pohon kapuk ke permukaan stainless steel sehingga memungkinkan terbentuknya lapisan pelindung untuk menurunkan laju korosi.
References
Aslam, R., Mobin, M., Zehra, S., & Aslam, J. (2022). A comprehensive review of corrosion inhibitors employed to mitigate stainless steel corrosion in different environments. In Journal of Molecular Liquids (Vol. 364). Elsevier B.V. https://doi.org/10.1016/j.molliq.2022.119992
Behloul, H., Ferkous, H., Bougdah, N., Djellali, S., Alam, M., Djilani, C., Sedik, A., Lerari, D., Jeon, B. H., & Benguerba, Y. (2022). New insights on the adsorption of CI-Reactive Red 141 dye using activated carbon prepared from the ZnCl2-treated waste cotton fibers: Statistical physics, DFT, COSMO-RS, and AIM studies. Journal of Molecular Liquids, 364. https://doi.org/10.1016/j.molliq.2022.119956
Dwivedi, D., Lepková, K., & Becker, T. (2017). Carbon steel corrosion: a review of key surface properties and characterization methods. RSC Advances, 7(8), 4580–4610. https://doi.org/10.1039/C6RA25094G
Elangovan, N., Srinivasan, A., Pugalmani, S., Kalaiyarasan, M., Rajendran, N., Seikh, A. H., & Rajendiran, N. (2024). Development and electrochemical investigations of enhanced corrosion-resistant Polyvinylcarbazole-TiO2 hybrid nanocomposite coatings on 316L SS for marine applications. Surface and Coatings Technology, 481. https://doi.org/10.1016/j.surfcoat.2024.130628
Ennafaa, F., Chraka, A., Tassaoui, K., Mouamr, I., Damej, M., Mahmoudi, A. E. L., Bougrin, K., Rahal, H. T., & Benmessaoud, M. (2025). An experimental and dual computational study using DFT and MD simulations to better understand the adsorption and corrosion-inhibiting properties of N-(3-(4-Methoxyphenyl) isoxazol-5-yl) methyl saccharin for C38 Steel in acidic medium. Materials Chemistry and Physics, 130441. https://doi.org/10.1016/j.matchemphys.2025.130441
En-Nylly, M., Skal, S., El aoufir, Y., Lgaz, H., Adnin, R. J., Alrashdi, A. A., Bellaouchou, A., Al-Hadeethi, M. R., Benali, O., Guedira, T., Lee, H. S., Kaya, S., & Ibrahim, S. M. (2023). Performance evaluation and assessment of the corrosion inhibition mechanism of carbon steel in HCl medium by a new hydrazone compound: Insights from experimental, DFT and first-principles DFT simulations. Arabian Journal of Chemistry, 16(6). https://doi.org/10.1016/j.arabjc.2023.104711
Fawzy, A., & Toghan, A. (2021). Inhibition evaluation of chromotrope dyes for the corrosion of mild steel in an acidic environment: thermodynamic and kinetic aspects. ACS Omega, 6(5), 4051.
Gapsari, F., Dewi, F. G. U., Wijaya, Setyarini, P. H., & Hidayatullah, S. (2020). The Effectiveness of Fish Scale Waste-Synthesized Chitosan and Food-Grade Chitosan as Corrosion Inhibitor. Journal of Southwest Jiaotong University, 55(2). https://doi.org/10.35741/issn.0258-2724.55.2.47
Gapsari, F., Utaminingrum, F., Lai, C. W., Anam, K., Sulaiman, A. M., Haidar, M. F., Julian, T. S., & Ebenso, E. E. (2024). A convolutional neural network -VGG16 method for corrosion inhibition of 304SS in sulfuric acid solution by timoho leaf extract. Journal of Materials Research and Technology, 30, 1116–1127. https://doi.org/10.1016/j.jmrt.2024.03.156
Hidayatullah, S., Sulaiman, A. M., & Iftitah, E. N. (2024). Durio Zibethinus Extract Performance as Corrosion Inhibitor in Simulated Seawater. Mechanics Exploration and Material Innovation, 1(1), 27–34. https://doi.org/10.21776/ub.memi.2024.001.01.4
Jebali, Z., Ferkous, H., Zerroug, M., Boublia, A., Delimi, A., Bouzid, A., Majdoub, H., Ernst, B., Elboughdiri, N., & Benguerba, Y. (2024). Unveiling the potent corrosion-inhibiting power of Ammophila arenaria aqueous extract for mild steel in acidic environments: An integrated experimental and computational study. Journal of Environmental Chemical Engineering, 12(2). https://doi.org/10.1016/j.jece.2024.112374
Kahkesh, H., Yeganeh, M., & Shahryari, Z. (2025). Algae-based corrosion inhibitors as innovative approaches to corrosion prevention: A review. In Algal Research (Vol. 89). Elsevier B.V. https://doi.org/10.1016/j.algal.2025.104071
Lahbabi, S., Bouferra, R., Saadi, L., & Khalil, A. (2025). Evaluation of Tamarix Aphylla extract as an eco-friendly corrosion inhibitor for carbon steel in saline medium. RSC Advances, 15(50), 42479–42492. https://doi.org/https://doi.org/10.1039/d5ra06912b
Liu, Y., Liu, J., Chen, B., & Ren, X. (2025). Investigation of three betaine surfactants and KI compounds as a corrosion inhibitor on carbon steel in industrial pickling. Journal of Molecular Structure, 141269. https://doi.org/10.1016/j.molstruc.2024.141269
Neupane, S., Losada-Pérez, P., Tiringer, U., Taheri, P., Desta, D., Xie, C., Crespo, D., Mol, A., Milošev, I., & Kokalj, A. (2021a). Study of mercaptobenzimidazoles as inhibitors for copper corrosion: Down to the molecular scale. J. Electrochem. Soc., 168(5), 051504.
Neupane, S., Losada-Pérez, P., Tiringer, U., Taheri, P., Desta, D., Xie, C., Crespo, D., Mol, A., Milošev, I., & Kokalj, A. (2021b). Study of mercaptobenzimidazoles as inhibitors for copper corrosion: Down to the molecular scale. J. Electrochem. Soc., 168(5), 051504.
Neupane, S., Losada-Pérez, P., Tiringer, U., Taheri, P., Desta, D., Xie, C., Crespo, D., Mol, A., Milošev, I., & Kokalj, A. (2021c). Study of mercaptobenzimidazoles as inhibitors for copper corrosion: Down to the molecular scale. J. Electrochem. Soc., 168(5), 051504.
Obot, I. B., Sorour, A. A., Verma, C., Al-Khaldi, T. A., & Rushaid, A. S. (2023). Key parameters affecting sweet and sour corrosion: Impact on corrosion risk assessment and inhibition. In Engineering Failure Analysis (Vol. 145). Elsevier Ltd. https://doi.org/10.1016/j.engfailanal.2022.107008
Oguzie, E. E., Enenebeaku, C. K., Akalezi, C. O., Okoro, S. C., Ayuk, A. A., & Ejike, E. N. (2010). Adsorption and Corrosion-Inhibiting Effect of Dacryodis Edulis Extract on Low-Carbon-Steel Corrosion in Acidic Media. J. Colloid Interface Sci., 349, 283.
Pesha, T., Mulaudzi, V. L., Cele, M. L., Mothapo, M. P., & Ratshisindi, F. (2023). Evaluation of corrosion inhibition effect of glycerol stearate on aluminium metal by electrochemical techniques. Arabian Journal of Chemistry, 16(7). https://doi.org/10.1016/j.arabjc.2023.104798
Quraishi, M. A., Chauhan, D. S., & Saji, V. S. (2020). 1 - Heterocyclic corrosion inhibitors. In M. A. Quraishi, D. S. Chauhan, & V. S. Saji (Eds.), Heterocyclic Organic Corrosion Inhibitors (pp. 1–19). Elsevier. https://doi.org/https://doi.org/10.1016/B978-0-12-818558-2.00001-1
saber, I., dahmani, K., Kharbouch, O., Aribou, Z., Ferraa, S., Alotaibi, N. H., El-alouani, M., Hsissou, R., Al-Maswari, B. M., Galai, M., Touhami, M. E., Aziz, Z., & El youbi, M. S. (2024). Enhancing copper corrosion resistance in highly caustic environments: Evaluation of environmentally friendly inorganic inhibitors and mechanistic insights. International Journal of Electrochemical Science, 19(11), 100815. https://doi.org/https://doi.org/10.1016/j.ijoes.2024.100815
Suryono, A. F., Ilman, M. N., Iswanto, P. T., & Ariyanto, T. (2025). Evaluation of Gambir extract as green corrosion inhibitor for API 5L X65 steel in 3.5 % NaCl solution containing 100 ppm NaHCO3. Results in Surfaces and Interfaces, 20. https://doi.org/10.1016/j.rsurfi.2025.100600
Thoume, A., Left, D. B., Elmakssoudi, A., Achagar, R., Dakir, M., Azzi, M., & Zertoubi, M. (2022). Performance evaluation of new chalcone oxime functionalized graphene oxide as a corrosion inhibitor for carbon steel in a hydrochloric acid solution. Langmuir, 38(24), 7472.
Wan, S., Zhang, T., Chen, H., Liao, B., & Guo, X. (2022). Kapok leaves extract and synergistic iodide as novel effective corrosion inhibitors for Q235 carbon steel in H2SO4 medium. Ind. Crops Prod., 178, 114649.
Zhang, J., Gong, X. L., Yu, H. H., & Du, M. (2011). The inhibition mechanism of imidazoline phosphate inhibitor for Q235 steel in hydrochloric acid medium. Corrosion Science, 53(10), 3324–3330. https://doi.org/10.1016/j.corsci.2011.06.008
Zhou, Z., Min, X., Wan, S., Liu, J., Liao, B., & Guo, X. (2023). A novel green corrosion inhibitor extracted from waste feverfew root for carbon steel in H2SO4 solution. Results in Engineering, 17. https://doi.org/10.1016/j.rineng.2023.100971
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